December 21, 2024

Safety in Chemical Industry: PART-2

Identification and classification of chemicals

Identification of chemicals begin with knowledge of basic chemistry.

Chemicals are classified in different ways.

They are broadly classified as organic and inorganic chemicals.

In organic are sub classified as metal and non metal.

Out of 104 elements, 80 are metals and majority of them are solid.

In non metal, more than half are gases.

Metals: aluminium, arsenic, calcium, chromium, cobalt etc.

Non metals: bromine, chlorine, flourine, iodine etc.

Organic chemicals include carbon compound.

They are sub classified as;

Aliphatic compound (without benzene rings): hydrocarbon, alcohol , ethers, ketons, aldehydes etc.

Aromatic: benzene, phenol, aromatic alcohol etc.

Heterocyclic compound and polymers (with other compound): furan, pyridine, thiophene etc.

Chemicals are also classified as under;

  1. According to physical state: solid, liquid or gas

2. Noxious gas:

Irritant gas: chlorine, ammonia, SO2

Systemic poison: benzene, nickel carbonyl etc.

Simple asphyxiate: nitrogen, methane, CO2

Chemical asphxiants: CO, hydrogen sulfide, HCN

3. Dust (P.M)

4. Biological agents and disease

Virus, bactaria, fugi, parasites etc.

The chemicals should be properly identified, classified and handled accordingly.

For this purpose some major divisions are given below;

Corrosive chemicals: bromine, caustic soda,flourine, sulfuric acid, sulfur chloride, hydrazine, phenol etc.

Oxidizing agent: aluminum nitrate, ammonium nitrate, perchlorate, zinc chlorate, zinc peroxide etc.

Carcinogens: asbestos, aniline, benzene, chloroform, carbon tetrachloride, styrene, phenol etc.

Poisonous chemicals: bromide, chloride, arsenic acid, cyclohexane, phenol, nickel cyanide, phosgene, DDT etc.

Pesticides- Insecticides: aldrine, acephate, BHC, cupric sulfate etc.

Explosive chemicals: carbon dust, aluminum dust, wood saw dust, potassium nitrate etc.

Solvents: methanol, ethanol, benzene, toluene etc.

Other flammable chemicals: LPG, ethylene, ethylene oxide, phosphorous, vinyl chloride etc.

Reactive chemicals: acetic acid, acetone, sodium, potassium, magnesium aluminium powder etc.

Alcohols: methyl, ethyl, amyl etc.

Refrigerant gases: ammonia, freon, carbon dioxide etc.

Esters: borate, benzoate, cynate

Ethers: thio ethers, vinyl ethers etc.

Enzymes: catalase, deaminase, lactose etc.

Resins: allyl, aminoplastic etc.

Acids:

In organic: hydorchloric, hydrobromic, hydrofloric etc.

Organic: acetic, acrylic, adipic, benzoic etc.

Compatible: means which can be stored or handled with that chemical to which it is compatible

Incompatible: means which should not be stored or handled with that chemicals to which it is incompatible.

ChemicalsIncompatible chemicals
AmmoniaMercury, chlorine, calcium hypochlorite, iodine, bromine and hydrogen floride
ChlorineAmmonia, acetylene, hydrogen, benzene
OxygenOils, grease, hydrogen,
PhosphursAir, oxygen
Sulfuric acidChlorate, per chlorates, permanganets

READ MORE :- MSDS/SDS section. -09 & Interpretation and use of MSDS/SDS

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