December 21, 2024

Handling and storage of E.O (Ethylene oxide)

Properties:

Colorless gas, MP -111 OC, BP 10.7 OC, LEL 3%, UEL 100%, TLV 1 ppm.

• It is toxic, flammable and explosive.

• Fire and explosion hazard when exposed to heat or flame.

• To fight fire use CO2, DCP or alcohol foam.

• It can react with acids and bases, ammonia, copper, mercaptans, potassium, alcohol, AlCl3, Al2O3 etc.

• Vaporizes rapidly at ambient temperature, can cause cold burns and it is soluble in water.

• PVC gloves, aprons, gum boots, goggles or face shield and BA set are necessary to handle E.O

Safety Measures

• Avoid heat, flame and ignition source.

• Dilute spillage with plenty of water.

• Provide nitrogen blanketing and preferably keep storage tank refrigerated.

• Its pressure should be kept within operating limits.

• Equipment cleaning may be done with citric acid.

• Prevent back flow of any chemical into EO vessel.

• Storage tanks should be separated and at least 15 meter from plants and buildings.

• Collusion of vehicles should be prevented by fencing and barricade.

• Spillage should be directed to remote catch pit by an impermeable and sloppy floor.

• It polymerizes by iron rust, acids, bases and by chlorides of iron and other metals.

• Polymerization is highly exothermic and may result in explosion.

• MOC: SS or MS

• Insulation: mineral wool covered by galvanised or SS cladding.

• Gasket should be teflon coated.

• Level gauges are float differential type, torque tube type or magnetic float type.

• Compound pressure and vacuum gauge is preferable.

• Temperature gauges with high and low alarm is necessary.

• Double safety valves with 2 mtr discharge outlet pipe, flame arrester on outlets and nitrogen purging connections are required.

• To prevent reverse flow of E.O, NRV and double block and bleed valve system is required.

• In emergency, start water system or ciruclate chilled water through limpet coils or use fire water hydrant system.

• Pump temperature should not rise by 3 degree C. therefore it should be kept cool by recycle from delivery to suction.

• A centrifugal pump with mechanical seal is normally used.

• To avoid accident of EO road tankers, provide driver with TREM CARD, DCP extinguisher, PVC hand gloves and respirators.

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